Butanal, Methylpropanal and MEK

Here are three compounds with the same molecular formula, C4H8O:

butanal (butyraldehyde) CH3CH2CH2HC=O , with b.p. 74.8oC and solubility 7.1%

2-methylpropanal (isobutyraldehyde) CH3CH(CH3)HC=O, with b.p. 65.9oC and solubility 10%

2-butanone (methyl ethyl ketone, or MEK) CH3C=OC2H5, with b.p. 79.6oC and solubility 27.5%

and here are their molecular structures: