Reactions of ethyl ether and 1-butanol

Ethyl ether , C2H5OC2H5 , has a solubility of 8g/100ml water, and a b.p. of 35oC.

1-butanol , CH3CH2CH2CH2OH , has a solubility of 8g/100ml water, and a b.p. of 117oC.

Ethyl ether is oxidised by very strong oxidants.

C2H5OC2H5 + HNO3 CH3COOH . . . . .

Ethyl ether reacts with hydrogen iodide.

C2H5OC2H5 + 2HI 2C2H5I + H2O

1-butanol is easily oxidised to butanoic acid:

CH3CH2CH2CH2OH + 2[O] CH3CH2CH2COOH + H2O

1-butanol reacts with hydrogen iodide forming iodibutane:

CH3CH2CH2CH2OH + HI CH3CH2CH2CH2I + H2O