A pheromone

Adult female mice produce a scent carrying a message (a pheromone) which delays the onset of puberty in immature females.

The pheromone contains these compounds, two of which are isomers. Which two?

1. (E)-3-hepten-6-one 2. (E)-2-hepten-6-one
3. heptan-2-one 4. 2,5-dimethylpyrazine
5. pentyl acetate 6. (Z)-3-pentenyl acetate

Numbers 1 and 2 are isomers. Each has formula C7H12O.