Rearranging octane to form iso-octane

.....................Octane, CH3CH2CH2CH2CH2CH2CH2CH3, is a straight-chain hydrocarbon with poor burning

.....................charactistics in a 4-stroke engine. It has an octane number of -19.

.....................How can the burning characteristics of octane be improved?

In the petroleum industry octane is passed through a catalytic cracker.

.................C8H18(g) C4H10(g) + C4H8(g)

.....................Octane, in this example, is producing butane and 1-butene or 2-butene.

Butane is catalytically rearranged to form methylpropane.

.................CH3CH2CH2CH3(g) (CH3)3CH(g)

Methylpropane is reacted with 2-butene forming iso-octane.

.................(CH3)3CH(g) + CH3CH=CHCH3(g)(CH3)3CCH2HC(CH3)2(g)

.....................The IUPAC name for iso-octane is 2,2,4-trimethylpentane. A different isomer of octane has been

......................produced and this one has better burning characteristics.